| 026Д | Chernivtsi — Odesa-Holovna | Departure 18:36 | Travel time 11 hr 50 min | Arrival 06:26 | |
| 037П | Uzhhorod — Odesa-Holovna | Departure 23:22 | Travel time 11 hr 33 min | Arrival 10:55 | |
| 168Л | Lviv — Odesa-Holovna | Departure 05:23 | Travel time 10 hr 51 min | Arrival 16:14 | |
| 026К | Yasynya — Odesa-Holovna | Departure 18:36 | Travel time 11 hr 50 min | Arrival 06:26 | |
| 037Л | Uzhhorod — Odesa-Holovna | Departure 23:22 | Travel time 11 hr 33 min | Arrival 10:55 | |
| 026Л | Yasynya — Odesa-Holovna | Departure 18:36 | Travel time 11 hr 50 min | Arrival 06:26 | |
| 136Л | Chernivtsi — Odesa-Holovna | Departure 18:36 | Travel time 11 hr 50 min | Arrival 06:26 | |
| 012Л | Lviv — Odesa-Holovna | Departure 17:46 | Travel time 10 hr 37 min | Arrival 04:23 |
Lviv station is located in the central part of the city of Lviv and was built in 1861. It is one of the largest railway stations in Ukraine and an important transportation hub. Today, the station features ticket offices for railway ticket sales, cafes, shops, and other services for passengers. The first train departed from Lviv station on April 15, 1861, marking an important date in the history of railway transport in Ukraine.
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as: