| 026О | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 11 hr 51 min | Arrival 04:10 | |
| 026П | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 11 hr 51 min | Arrival 04:10 | |
| 038О | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 11 hr 39 min | Arrival 00:24 | |
| 012Ш | Odesa-Holovna — Lviv | Departure 17:46 | Travel time 10 hr 32 min | Arrival 04:18 | |
| 026Ш | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 11 hr 51 min | Arrival 04:10 | |
| 136Ш | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 11 hr 51 min | Arrival 04:10 | |
| 038Ш | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 11 hr 39 min | Arrival 00:24 | |
| 168О | Odesa-Holovna — Lviv | Departure 07:52 | Travel time 10 hr 45 min | Arrival 18:37 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as:
Lviv station is located in the central part of the city of Lviv and was built in 1861. It is one of the largest railway stations in Ukraine and an important transportation hub. Today, the station features ticket offices for railway ticket sales, cafes, shops, and other services for passengers. The first train departed from Lviv station on April 15, 1861, marking an important date in the history of railway transport in Ukraine.