| 060Ш | Odesa-Holovna — Kharkiv-Pas | Departure 18:58 | Travel time 2 hr 31 min | Arrival 21:29 | |
| 192Ш | Odesa-Holovna — Kramatorsk | Departure 18:58 | Travel time 2 hr 31 min | Arrival 21:29 | |
| 052Ш | Odesa-Holovna — Zaporizhzhya 1 | Departure 19:10 | Travel time 2 hr 32 min | Arrival 21:42 | |
| 038О | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 2 hr 32 min | Arrival 15:17 | |
| 106Ш | Odesa-Holovna — Kyiv-Pasazhyrsky | Departure 19:30 | Travel time 2 hr 27 min | Arrival 21:57 | |
| 054Л | Odesa-Holovna — Dnipro-Holovny | Departure 19:10 | Travel time 2 hr 32 min | Arrival 21:42 | |
| 026О | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 2 hr 39 min | Arrival 18:58 | |
| 026П | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 2 hr 39 min | Arrival 18:58 | |
| 054Ш | Odesa-Holovna — Dnipro-Holovny | Departure 19:10 | Travel time 2 hr 32 min | Arrival 21:42 | |
| 254Ш | Odesa-Holovna — Kryvy Rih-Holovny | Departure 19:10 | Travel time 2 hr 32 min | Arrival 21:42 | |
| 078Ш | Odesa-Holovna — Kovel | Departure 15:03 | Travel time 2 hr 35 min | Arrival 17:38 | |
| 026Ш | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 2 hr 39 min | Arrival 18:58 | |
| 136Ш | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 2 hr 39 min | Arrival 18:58 | |
| 148Ш | Odesa-Holovna — Kyiv-Pasazhyrsky | Departure 15:23 | Travel time 2 hr 30 min | Arrival 17:53 | |
| 038Ш | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 2 hr 32 min | Arrival 15:17 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as:
Podilsk Station is one of the largest and most beautiful railway stations in Ukraine. It was established in 1874, and the first train departed from it to Kyiv on June 1, 1874. The station has two railway platforms and provides convenient rail connections between Podilsk and other regions of Ukraine.