| 026О | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 7 hr 38 min | Arrival 23:57 | |
| 026П | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 7 hr 38 min | Arrival 23:57 | |
| 038О | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 7 hr 15 min | Arrival 20:00 | |
| 012Ш | Odesa-Holovna — Lviv | Departure 17:46 | Travel time 6 hr 41 min | Arrival 00:27 | |
| 026Ш | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 7 hr 38 min | Arrival 23:57 | |
| 136Ш | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 7 hr 38 min | Arrival 23:57 | |
| 038Ш | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 7 hr 15 min | Arrival 20:00 | |
| 168О | Odesa-Holovna — Lviv | Departure 07:52 | Travel time 6 hr 46 min | Arrival 14:38 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as:
The station Khmelnytskyi is located in the city of Khmelnytskyi, situated on the Podilsk Plain in southern Ukraine. It is the administrative center of Khmelnytskyi Oblast and one of the largest cities in the western part of the country. The city boasts a rich cultural heritage, with a history spanning over 600 years — dating back to 1362. Khmelnytskyi serves important functions as both an industrial and cultural center of the region, contributing to economic development and the preservation of traditions.