| 026О | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 8 hr 44 min | Arrival 01:03 | |
| 026П | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 8 hr 44 min | Arrival 01:03 | |
| 038О | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 8 hr 27 min | Arrival 21:12 | |
| 026Ш | Odesa-Holovna — Yasynya | Departure 16:19 | Travel time 8 hr 44 min | Arrival 01:03 | |
| 136Ш | Odesa-Holovna — Chernivtsi | Departure 16:19 | Travel time 8 hr 44 min | Arrival 01:03 | |
| 038Ш | Odesa-Holovna — Uzhhorod | Departure 12:45 | Travel time 8 hr 27 min | Arrival 21:12 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as:
The Volochysk station is located in the Khmelnytskyi region on the Shepetivka - Yuzhna railway line. It was built in 1873 and currently serves as an important hub in Ukraine's railway network. The Volochysk station serves not only passenger trains but also facilitates freight transportation. The first train departed from Volochysk station in 1873, emphasizing its historical significance and role in the region's transport infrastructure.