| 026О | Odesa-Holovna — Yasynya | Departure 01:05 | Travel time 3 hr 5 min | Arrival 04:10 | |
| 026П | Odesa-Holovna — Chernivtsi | Departure 01:05 | Travel time 3 hr 5 min | Arrival 04:10 | |
| 038О | Odesa-Holovna — Uzhhorod | Departure 21:14 | Travel time 3 hr 10 min | Arrival 00:24 | |
| 026Ш | Odesa-Holovna — Yasynya | Departure 01:05 | Travel time 3 hr 5 min | Arrival 04:10 | |
| 136Ш | Odesa-Holovna — Chernivtsi | Departure 01:05 | Travel time 3 hr 5 min | Arrival 04:10 | |
| 038Ш | Odesa-Holovna — Uzhhorod | Departure 21:14 | Travel time 3 hr 10 min | Arrival 00:24 | |
| 073О | Kharkiv-Pas — Przemysl-Glowny | Departure 02:50 | Travel time 3 hr 24 min | Arrival 06:14 | |
| 089К | Kyiv-Pasazhyrsky — Przemysl-Glowny | Departure 02:50 | Travel time 3 hr 24 min | Arrival 06:14 | |
| 128П | Zaporizhzhya 1 — Lviv | Departure 06:53 | Travel time 3 hr 31 min | Arrival 10:24 | |
| 081Д | Kyiv-Pasazhyrsky — Uzhhorod | Departure 23:11 | Travel time 3 hr 20 min | Arrival 02:31 | |
| 126О | Kremenchuk — Mukacheve | Departure 05:29 | Travel time 2 hr 59 min | Arrival 08:28 | |
| 081К | Kyiv-Pasazhyrsky — Uzhhorod | Departure 23:11 | Travel time 3 hr 20 min | Arrival 02:31 |
The Volochysk station is located in the Khmelnytskyi region on the Shepetivka - Yuzhna railway line. It was built in 1873 and currently serves as an important hub in Ukraine's railway network. The Volochysk station serves not only passenger trains but also facilitates freight transportation. The first train departed from Volochysk station in 1873, emphasizing its historical significance and role in the region's transport infrastructure.
Lviv station is located in the central part of the city of Lviv and was built in 1861. It is one of the largest railway stations in Ukraine and an important transportation hub. Today, the station features ticket offices for railway ticket sales, cafes, shops, and other services for passengers. The first train departed from Lviv station on April 15, 1861, marking an important date in the history of railway transport in Ukraine.