| 748П | Ternopil — Kyiv-Pasazhyrsky | Departure 05:22 | Travel time 5 hr 23 min | Arrival 10:45 | |
| 081П | Uzhhorod — Kyiv-Pasazhyrsky | Departure 23:48 | Travel time 6 hr 44 min | Arrival 06:32 | |
| 748Ш | Ternopil — Kyiv-Pasazhyrsky | Departure 05:22 | Travel time 5 hr 23 min | Arrival 10:45 | |
| 081Л | Uzhhorod — Kyiv-Pasazhyrsky | Departure 23:48 | Travel time 6 hr 44 min | Arrival 06:32 | |
| 090К | Przemysl-Glowny — Kyiv-Pasazhyrsky | Departure 19:40 | Travel time 7 hr 21 min | Arrival 03:01 | |
| 474О | Przemysl-Glowny — Kharkiv-Pas | Departure 21:12 | Travel time 7 hr 53 min | Arrival 05:05 | |
| 074О | Przemysl-Glowny — Kharkiv-Pas | Departure 19:40 | Travel time 7 hr 21 min | Arrival 03:01 | |
| 070К | Przemysl-Glowny — Poltava-Pivdenna | Departure 00:18 | Travel time 5 hr 38 min | Arrival 05:56 | |
| 131Ш | Uzhhorod — Poltava-Pivdenna | Departure 00:18 | Travel time 5 hr 38 min | Arrival 05:56 | |
| 129Л | Uzhhorod — Poltava-Pivdenna | Departure 00:18 | Travel time 5 hr 38 min | Arrival 05:56 |
The Volochysk station is located in the Khmelnytskyi region on the Shepetivka - Yuzhna railway line. It was built in 1873 and currently serves as an important hub in Ukraine's railway network. The Volochysk station serves not only passenger trains but also facilitates freight transportation. The first train departed from Volochysk station in 1873, emphasizing its historical significance and role in the region's transport infrastructure.
The Kyiv-Pasazhyrskyi station is located in Kyiv, the capital of Ukraine. It is one of the largest and most convenient railway stations in the country. Kyiv-Pasazhyrskyi serves as an important transportation hub for many destinations throughout Ukraine, as well as for international trips. The station's history dates back to 1870 when a wooden structure was built here. In 1912, a new stone terminal in the modern style was constructed, which is impressive even today. Currently, Kyiv-Pasazhyrskyi occupies a large area, has several platforms, and features a comfortable lobby equipped with convenient waiting areas for passengers.
Numerous hotels, cafes, and shops are located around the station. Among the well-known establishments is the restaurant "Tsar," which offers traditional Ukrainian cuisine, as well as the cafe "Shokoladnytsia," where visitors can enjoy delicious coffee. For travelers planning to stay overnight, several recommended hotels are nearby, such as "Turyst" and "Premier Hotel Rus." Additionally, thanks to the developed transportation infrastructure, it is easy to reach the station by metro or bus from any part of the capital.